A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions
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| dc.contributor.author | Kleinhans, George
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| dc.contributor.author | Guisado-Barrios, Gregorio
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| dc.contributor.author | Liles, David C.
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| dc.contributor.author | Bertrand, Guy
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| dc.contributor.author | Bezuidenhout, Daniela Ina
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| dc.date.accessioned | 2016-05-05T13:06:45Z | |
| dc.date.issued | 2016-01 | |
| dc.description.abstract | An air-stable rhodium(I)-oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homodimerization and hydrothiolation of alkynes, affording the gemenyne and α-vinyl sulfide isomers, respectively, with excellent selectivity. A one-pot stepwise strategy allows the selective catalytic preparation of non-symmetric bis-vinyl sulfides, as well as the alkyne dimerization-hydrothiolation tandem reaction. | en_ZA |
| dc.description.department | Chemistry | en_ZA |
| dc.description.embargo | 2017-01-31 | |
| dc.description.librarian | hb2016 | en_ZA |
| dc.description.uri | http://www.rsc.org/journals-books-databases/about-journals/chemcomm | en_ZA |
| dc.identifier.citation | Kleinhans, G, Guisado-Barrios, G, Liles, DC, Bertrand, G & Bezuidenhout, DI 2016, 'A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions', Chemical Communications, vol. 52, no. 17, pp. 3504-3507. | en_ZA |
| dc.identifier.issn | 1359-7345 (print) | |
| dc.identifier.issn | 1364-548X (online) | |
| dc.identifier.other | 10.1039/C6CC00029K | |
| dc.identifier.uri | http://hdl.handle.net/2263/52488 | |
| dc.language.iso | en | en_ZA |
| dc.publisher | Royal Society of Chemistry | en_ZA |
| dc.rights | © The Royal Society of Chemistry 2016 | en_ZA |
| dc.subject | Rhodium(I)–oxygen | en_ZA |
| dc.subject | Catalyzes | en_ZA |
| dc.subject | Hydrothiolation | en_ZA |
| dc.subject | Alkynes | en_ZA |
| dc.title | A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions | en_ZA |
| dc.type | Postprint Article | en_ZA |
