dc.contributor.author |
Kleinhans, George
|
|
dc.contributor.author |
Guisado-Barrios, Gregorio
|
|
dc.contributor.author |
Liles, David C.
|
|
dc.contributor.author |
Bertrand, Guy
|
|
dc.contributor.author |
Bezuidenhout, Daniela Ina
|
|
dc.date.accessioned |
2016-05-05T13:06:45Z |
|
dc.date.issued |
2016-01 |
|
dc.description.abstract |
An air-stable rhodium(I)-oxygen adduct featuring a CNC-pincer
ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homodimerization
and hydrothiolation of alkynes, affording the gemenyne
and α-vinyl sulfide isomers, respectively, with excellent
selectivity. A one-pot stepwise strategy allows the selective
catalytic preparation of non-symmetric bis-vinyl sulfides, as well
as the alkyne dimerization-hydrothiolation tandem reaction. |
en_ZA |
dc.description.department |
Chemistry |
en_ZA |
dc.description.embargo |
2017-01-31 |
|
dc.description.librarian |
hb2016 |
en_ZA |
dc.description.uri |
http://www.rsc.org/journals-books-databases/about-journals/chemcomm |
en_ZA |
dc.identifier.citation |
Kleinhans, G, Guisado-Barrios, G, Liles, DC, Bertrand, G & Bezuidenhout, DI 2016, 'A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions', Chemical Communications, vol. 52, no. 17, pp. 3504-3507. |
en_ZA |
dc.identifier.issn |
1359-7345 (print) |
|
dc.identifier.issn |
1364-548X (online) |
|
dc.identifier.other |
10.1039/C6CC00029K |
|
dc.identifier.uri |
http://hdl.handle.net/2263/52488 |
|
dc.language.iso |
en |
en_ZA |
dc.publisher |
Royal Society of Chemistry |
en_ZA |
dc.rights |
© The Royal Society of Chemistry 2016 |
en_ZA |
dc.subject |
Rhodium(I)–oxygen |
en_ZA |
dc.subject |
Catalyzes |
en_ZA |
dc.subject |
Hydrothiolation |
en_ZA |
dc.subject |
Alkynes |
en_ZA |
dc.title |
A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions |
en_ZA |
dc.type |
Postprint Article |
en_ZA |