pH-based control strategies for the nitrification of high-ammonium wastewaters

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Authors

Van Rooyen, Ignatius Leopoldus
Brink, Hendrik Gideon
Nicol, Willie

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Publisher

MDPI

Abstract

Aquatic nitrogen pollution is one of the most urgent environmental issues requiring prevention and mitigation. Large quantities of high-ammonium wastewaters are generated by several industrial sectors, such as fertilizer and anaerobic-digestion plants. Nitrification of these wastewaters is commonly carried out, either to remove nitrogen or produce liquid fertilizers. Standard control methodologies for the efficient nitrification of high-ammonium wastewaters to produce liquid fertilizers have not yet been established and are still within their early stages of development. In this paper, novel pH-based control algorithms are presented that maintain operation at the microbial maximum reaction rate (umax) in batch and continuous reactors. Complete conversion of ammonium to nitrate was achieved in a batch setup, and a conversion of 93% (1%) was achieved in a continuously-stirred-tank-reactor. The unparalleled performance and affordability of the control schemes proposed offer a steppingstone to the future of sustainable fertilizer production.

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Keywords

Ammonium, Nitrate, Proton, Hydroponic, Wastewater, Aquatic nitrogen pollution, High-ammonium wastewaters

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Citation

Van Rooyen, I.L., Brink, H.G. & Nicol, W. pH-Based Control Strategies for the Nitrification of High-Ammonium Wastewaters. Fermentation 2021, 7, 319. https://DOI.org/10.3390/fermentation7040319.