Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide : a stabilizing pincer ligand for reactive late transition metal complexes

Bezuidenhout, Daniela Ina; Kleinhans, George; Guisado-Barrios, Gregorio; Liles, David C.; Ung, Gael; Bertrand, Guy

dc.contributor.author	Bezuidenhout, Daniela Ina
dc.contributor.author	Kleinhans, George
dc.contributor.author	Guisado-Barrios, Gregorio
dc.contributor.author	Liles, David C.
dc.contributor.author	Ung, Gael
dc.contributor.author	Bertrand, Guy
dc.date.accessioned	2014-03-07T10:10:02Z
dc.date.issued	2014-03
dc.description.abstract	The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(ii)-hydride, and an unusual Cu(ii) complex displaying a seesaw geometry, have been isolated.	en
dc.description.librarian	hb2014	en
dc.description.librarian	ai2014
dc.description.sponsorship	The National Research Foundation of South Africa, (DIB, Grant number 76226), the Fulbright Scholar Program (DIB), and the DOE (GB, DE-FG02-13ER16370).	en
dc.description.uri	http://www.rsc.org/chemcomm	en
dc.identifier.citation	Bezuidenhout, DI, Kleinhans, G, Guisado-Barrios, G, Liles, DC, Ung, G & Bertrand, G 2014, 'Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide : a stabilizing pincer ligand for reactive late transition metal complexes', Chemical Communications, vol. 50, no. 19, pp. 2431-2433.	en
dc.identifier.issn	1359-7345 (print)
dc.identifier.issn	1364-548X (online)
dc.identifier.other	10.1039/c3cc49385g
dc.identifier.uri	http://hdl.handle.net/2263/37095
dc.language.iso	en	en
dc.publisher	Royal Society of Chemistry	en
dc.rights	© The Royal Society of Chemistry 2014	en
dc.subject	Isolation of a potassium	en
dc.subject	Stabilizing pincer ligand	en
dc.subject	Transition metal complexes	en
dc.subject.lcsh	Potassium compounds	en
dc.subject.lcsh	Ligand field theory	en
dc.subject.lcsh	Ligands (Biochemistry)	en
dc.subject.lcsh	Transition metals	en
dc.title	Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide : a stabilizing pincer ligand for reactive late transition metal complexes	en
dc.type	Postprint Article	en