Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide : a stabilizing pincer ligand for reactive late transition metal complexes

dc.contributor.authorBezuidenhout, Daniela Ina
dc.contributor.authorKleinhans, George
dc.contributor.authorGuisado-Barrios, Gregorio
dc.contributor.authorLiles, David C.
dc.contributor.authorUng, Gael
dc.contributor.authorBertrand, Guy
dc.contributor.emaildaniela.bezuidenhout@up.ac.zaen
dc.date.accessioned2014-03-07T10:10:02Z
dc.date.issued2014-03
dc.description.abstractThe synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(ii)-hydride, and an unusual Cu(ii) complex displaying a seesaw geometry, have been isolated.en
dc.description.librarianhb2014en
dc.description.librarianai2014
dc.description.sponsorshipThe National Research Foundation of South Africa, (DIB, Grant number 76226), the Fulbright Scholar Program (DIB), and the DOE (GB, DE-FG02-13ER16370).en
dc.description.urihttp://www.rsc.org/chemcommen
dc.identifier.citationBezuidenhout, DI, Kleinhans, G, Guisado-Barrios, G, Liles, DC, Ung, G & Bertrand, G 2014, 'Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide : a stabilizing pincer ligand for reactive late transition metal complexes', Chemical Communications, vol. 50, no. 19, pp. 2431-2433.en
dc.identifier.issn1359-7345 (print)
dc.identifier.issn1364-548X (online)
dc.identifier.other10.1039/c3cc49385g
dc.identifier.urihttp://hdl.handle.net/2263/37095
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.rights© The Royal Society of Chemistry 2014en
dc.subjectIsolation of a potassiumen
dc.subjectStabilizing pincer liganden
dc.subjectTransition metal complexesen
dc.subject.lcshPotassium compoundsen
dc.subject.lcshLigand field theoryen
dc.subject.lcshLigands (Biochemistry)en
dc.subject.lcshTransition metalsen
dc.titleIsolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide : a stabilizing pincer ligand for reactive late transition metal complexesen
dc.typePostprint Articleen

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