Self-isomerized−cyclometalated rhodium NHC complexes as active catalysts in the hydrosilylation of internal alkynes

Van Vuuren, EstefanMalan, F.P. (Frederick)Cordier, WernerNell, Margo JudithLandman, Marile2023-07-142023-07-142022-02Van Vuuren, E., Malan, F.P., Cordier, W. et al. 2022, 'Self-isomerized−cyclometalated rhodium NHC complexes as active catalysts in the hydrosilylation of internal alkynes', Organometallics, vol. 41, no. 3, pp. 187-200, doi : 10.1021/acs.organomet.1c00409.0276-7333 (print)1520-6041 (online)10.1021/acs.organomet.1c00409http://hdl.handle.net/2263/91457ACCESSION CODES : CCDC 2065431–2065437 and 2081484 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.Please read abstract in the article.enThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, © 2022 American Chemical Society after peer review and technical editing by the publisher.CatalystsHydrocarbonsLigandsMolecular structureSelectivitySelf-isomerized−cyclometalated rhodium NHC complexes as active catalysts in the hydrosilylation of internal alkynesPostprint Article