Simonkolleite-graphene foam composites and their superior electrochemical performance

dc.contributor.authorMomodu, Damilola Y.
dc.contributor.authorBarzegar, Farshad
dc.contributor.authorBello, Abdulhakeem
dc.contributor.authorDangbegnon, Julien K.
dc.contributor.authorMasikhwa, T.M. (Tshifhiwa)
dc.contributor.authorMadito, M.J. (Moshawe)
dc.contributor.authorManyala, Ncholu I.
dc.contributor.emailncholu.manyala@up.ac.zaen_ZA
dc.date.accessioned2015-01-30T07:30:24Z
dc.date.available2015-01-30T07:30:24Z
dc.date.issued2015-01
dc.description.abstractSimonkolleite-graphene foam (SimonK/GF) composite has been synthesized by a facile solvothermal and environmentally friendly technique with excellent electrochemical properties. The obtained product was initially analyzed by scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), Fourier transform infrared resonance (FTIR) spectroscopy and cyclic voltammetry (CV) techniques. The microscopy results reveal hexagonal sheets interlaced with each other and adjacent graphene sheets. The existence of graphene foam in the simonK/GF composite is further confirmed from the structural and the optical characteristics obtained from XRD and FTIR respectively. The BET results obtained indicate an improvement in the surface area due to the addition of graphene foam to a value of 39.58 m2 g 1. The N2 adsorption/desorption also shows the presence of active mesopores required for charge transport. As a promising electrode material for supercapacitors, the composite shows a high specific capacitance value of 1094 F/g at 1 A/g with a coulombic efficiency of 100% after 1000 cycles. These results show a potential for adoption of this composite in energy storage applications.en_ZA
dc.description.librarianhb2015en_ZA
dc.description.sponsorshipSouth African Research Chairs Initiative (SARChi) of the Department of Science and Technology (DST) and the National Research Foundation (NRF).en_ZA
dc.description.urihttp://www.elsevier.com/locate/electactaen_ZA
dc.identifier.citationMomodu, DY, Barzegar, F, Bello, A, Dangbegnon, JK, Masikhwa, T, Madito, J & Manyala, NI 2015, 'Simonkolleite-graphene foam composites and their superior electrochemical performance', Electrochimica Acta, vol. 151, no. 1, pp. 591-598.en_ZA
dc.identifier.issn0013-4686 (print)
dc.identifier.issn1873-3859 (online)
dc.identifier.other10.1016/j.electacta.2014.11.015
dc.identifier.urihttp://hdl.handle.net/2263/43501
dc.language.isoenen_ZA
dc.publisherElsevieren_ZA
dc.rights© 2014 Published by Elsevier Ltd. All rights. Notice : this is the author’s version of a work that was accepted for publication in Electrochimica Acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Electrochimica Acta, vol. 151, no. 1, pp. 591-598, 2015. doi : 10.1016/j.electacta.2014.11.015.en_ZA
dc.subjectSimonkolleite sheetsen_ZA
dc.subjectGraphene foamen_ZA
dc.subjectCompositesen_ZA
dc.subjectSupercapacitoren_ZA
dc.subjectSimonkolleite-graphene foam (SimonK/GF)en_ZA
dc.titleSimonkolleite-graphene foam composites and their superior electrochemical performanceen_ZA
dc.typePostprint Articleen_ZA

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