Properties of layered double hydroxide micro- and nanocomposites
| dc.contributor.author | Moyo, Lumbidzani | |
| dc.contributor.author | Focke, Walter Wilhelm | |
| dc.contributor.author | Heidenreich, D. | |
| dc.contributor.author | Labuschagne, F.J.W.J. (Frederick Johannes Willem Jacobus) | |
| dc.contributor.author | Radusch, Hans-Joachim | |
| dc.contributor.email | walter.focke@up.ac.za | en |
| dc.date.accessioned | 2013-04-05T17:05:36Z | |
| dc.date.available | 2013-04-05T17:05:36Z | |
| dc.date.issued | 2013-03 | |
| dc.description.abstract | Carbonate and stearate intercalated layered double hydroxides were used as fillers to prepare polymer micro- and nanocomposites, respectively. The stearate modified starting material was bilayerintercalated clay. During melt compounding excess stearates were released and the clay reverted to a monolayer-intercalated form. The exuded stearate acted as a lubricant lowering the melt viscosity of poly(ethylene-co-vinyl acetate) and linear low density polyethylene matrices. Strong hydrogen bond interactions between the chains of poly(ethylene-co-vinyl alcohol) and the clay platelet surfaces overwhelmed the lubrication effect and caused an increase in the melt viscosity of this matrix. The notched Charpy impact strength of this composite is almost double that of the neat polymer. It appears that this can be attributed to the ability of the highly dispersed and randomly oriented nano-sized clay platelets to promote extensive internal micro-cavitation during impact loading. The creation of a large internal surface area provided the requisite energy dissipation mechanism. | en |
| dc.description.librarian | hj2013 | en |
| dc.description.librarian | ai2013 | en |
| dc.description.sponsorship | The National Research Foundation (NRF) and the Bundesministerium fur Forschung (BMBF) | en |
| dc.description.uri | http://www.elsevier.com/locate/matresbu | en |
| dc.identifier.citation | Moyo, L, Focke, WW, Heidenreich, D, Labuschagne, FJWJ & Radusch, HJ 2013, 'Properties of layered double hydroxide micro- and nanocomposites', Materials Research Bulletin, vol. 48, no. 3, pp. 1218-1227. | en |
| dc.identifier.issn | 0025-5408 (print) | |
| dc.identifier.issn | 1873-4227 (online) | |
| dc.identifier.other | 10.1016/j.materresbull.2012.11.040 | |
| dc.identifier.uri | http://hdl.handle.net/2263/21253 | |
| dc.language.iso | en | en |
| dc.publisher | Elsevier | en |
| dc.rights | © 2012 Elsevier. All rights reserved. Notice : this is the author’s version of a work that was accepted for publication in Materials Research Bulletin. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Materials Research Bulletin, vol. 48, no. 3, pp. 1218-1227, 2013. | en |
| dc.subject | Composites | en |
| dc.subject | Layered compounds | en |
| dc.subject | Intercalation reactions | en |
| dc.subject | Electron microscopy | en |
| dc.subject.lcsh | Layered double hydroxide (LDH) | en |
| dc.subject.lcsh | Nanocomposites (Materials) | en |
| dc.subject.lcsh | Stearates | en |
| dc.subject.lcsh | Polymeric composites | en |
| dc.title | Properties of layered double hydroxide micro- and nanocomposites | en |
| dc.type | Postprint Article | en |