Improving the thermal stability of fly ash-based geopolymer materials through cellulose nanocrystal reinforcement

Abstract

Prior to this study, the thermal stability of fly ash-based geopolymer (FAG) construction materials as a function of cellulose nanocrystal (CNC) concentration and the optimal CNC dosage leading to thermal stability have not been investigated. This study investigates the influence of CNC reinforcement and curing duration on the thermal stability of FAG geopolymer. A series of samples incorporating CNC dosages ranging from 0 to 1.86 wt.% were prepared and subjected to 24- and 48-h curing regimes to evaluate their thermal degradation behaviors. Thermogravimetric analysis (TGA) revealed that 24-h-cured samples exhibited steeper weight losses compared to 48-h-cured ones, particularly in the 100–600 ℃ range. This trend was attributed to incomplete stabilization of organics in shorter curing times. Among all dosages, the 48-h-cured 1.7 wt.% CNC sample demonstrated the lowest total weight loss (~ 9.6% lower than the control), indicating enhanced thermal resistance. Derivative weight analysis further confirmed this, showing the lowest peak weight change rate (0.105%/℃) for the 1.7 wt.% CNC sample cured for 48 h, compared to 0.304%/℃ for the unreinforced control. Additionally, differential scanning calorimetry (DSC) indicated reduced exothermic heat flow in 48-h-cured samples, especially in the 1.7 wt.% CNC formulation, suggesting minimal phase transitions and improved thermal reliability. The novelty of this work lies in demonstrating the synergistic enhancement of thermal resistance through CNC addition and extended curing. Unlike prior studies that primarily focused on mechanical reinforcement, this research establishes an optimal CNC dosage (1.7 wt%) that minimizes thermal degradation, offering critical insights for thermally stable, bio-reinforced geopolymer development. These findings support the application of CNC–geopolymer composites in fire-resistant, sustainable construction materials.