2,2'-(Piperazine-1,4-diyl)diethanaminium dibenzoate

dc.contributor.authorCukrowski, Ignacy
dc.contributor.authorAdeyinka, Adedapo S.
dc.contributor.authorLiles, David C.
dc.contributor.emailignacy.cukrowski@up.ac.zaen
dc.date.accessioned2013-03-20T13:45:37Z
dc.date.available2013-03-20T13:45:37Z
dc.date.issued2012-07-02
dc.descriptionSupplementary data and figures for this paper are available from the IUCr electronic archives (Reference: JJ2134).en
dc.description.abstractThe asymmetric unit of the title salt C8H22N4 2+2C7H5O2 , comprises two independent pairs of half a 2,2'-(piperazine-1,4- diyl)diethanaminium dication plus a benzoate anion. The dications are symmetrical and lie across crystallographic centres of inversion. The crystal structure was refined as a two-component pseudo-merohedral twin using the twin law 001 010 100 [he domain fractions are 0.8645 (8) and 0.1355 (8)]. The anions and cations are linked by N—H...O hydrogen bonds and weak N—H...O intermolecular interactions to form infinite two-dimensional networks parallel to [101]. The conformation adopted by the cation in the crystal structure is very similar to that adopted by the same cation in the structures of the 2-hydroxybenzoate [Cukrowski et al. (2012). Acta Cryst, E68, o2387], the nitrate and the tetrahydrogen pentaborate salts.en
dc.description.librarianam2013en
dc.description.librarianai2013
dc.description.sponsorshipThe authors thank Dr John E. Davies of the University of Cambridge (England) for the data collection.en
dc.description.urihttp://journals.iucr.org/e/journalhomepage.htmlen
dc.identifier.citationCukrowski, I, Adeyinka, AS & Liles, DC 2012, '2,2'-(Piperazine-1,4-diyl)diethanaminium dibenzoate', Acta Crystallographica Section E-Structure Reports Online, vol. E68, no. o2389, pp. sup-1-8.en
dc.identifier.issn1600-5368
dc.identifier.other10.1107/S1600536812030115
dc.identifier.urihttp://hdl.handle.net/2263/21195
dc.language.isoenen
dc.publisherInternational Union of Crystallographyen
dc.rightsInternational Union of Crystallographyen
dc.subjectSingle-crystal X-ray studyen
dc.subjectT = 180 Ken
dc.subjectMean (C–C) = 0.002 Aen
dc.subjectR factor = 0.040en
dc.subjectwR factor = 0.110en
dc.subjectData-to-parameter ratio = 17.9en
dc.subject.lcshCrystallizationen
dc.subject.lcshCrystalsen
dc.subject.lcshCrystallographyen
dc.title2,2'-(Piperazine-1,4-diyl)diethanaminium dibenzoateen
dc.typeArticleen

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