Fabrication and characterization of clay-polyethylene composite opted for shielding of ionizing radiation

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Authors

Olukotun, S.F.
Gbenu, S.T.
Oyedotun, Kabir Oyeniran
Fasakin, Oladepo
Akindoyin, G.O.
Shittu, H.O.
Fasasi, M.K.
Khandaker, Mayeen Uddin
Osman, Hamid
Elesawy, Basem H.

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Publisher

MDPI

Abstract

This study fabricated and characterized a self-sustaining hydrogenous content claypolyethylene composite opted for ionizing radiation shielding. Composites designated A–G were fabricated each containing 0–30 wt% of recycled low density polyethylene (LDPE), respectively. To know the effects of the incorporated LDPE on the morphology, microstructural, compressive strength, thermal property and displacement effect on the vital elements were studied using scanning electron microscopy (SEM), X-ray diffractometry (XRD), universal mechanical testing machine, differential thermal analysis (DTA), Rutherford backscattering (RBS) technique and particle induced X-ray emission (PIXE), respectively. The bulk densities of the clay composites ranged between 1.341 and 2.030 g/cm3. The samples’ XRD analysis revealed similar patterns, with a sharp and prominent peak at angle 2 equals ~26.11 , which matched with card number 16-0606 of the Joint Committee on Powder Diffraction Standards (JCPDS) that represents Aluminum Silicate Hydroxide (Al2Si2O5(OH)4), a basic formula for Kaolin clay. The compressive strength ranged between 2.52 and 5.53 MPa. The ratio of Si to Al in each composite is about 1:1. The dehydroxylation temperature for samples ranged between 443.23 C and 555.23 C.

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Keywords

Low density polyethylene (LDPE), Clay composites, Radiation shielding, Scanning electron microscopy (SEM), X-ray diffractometry (XRD), Universal mechanical testing machine, Rutherford backscattering (RBS), Differential thermal analysis (DTA), Particle induced X-ray emission (PIXE)

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Citation

Olukotun, S.F.; Gbenu, S.T.; Oyedotun, K.O.; Fasakin, O.; Sayyed, M.I.; Akindoyin, G.O.; Shittu, H.O.; Fasasi, M.K.; Khandaker, M.U.; Osman, H.; et al. Fabrication and Characterization of Clay-Polyethylene Composite Opted for Shielding of Ionizing Radiation. Crystals 2021, 11, 1068. https://DOI.org/ 10.3390/cryst11091068.