Accelerated photo-oxidation of Polyamide 11 nanocomposites under various clays nanofillers
| dc.contributor.author | Dehouche, Nadjet | |
| dc.contributor.author | Kaci, Mustapha | |
| dc.contributor.author | Focke, Walter Wilhelm | |
| dc.contributor.author | Van der Merwe, Liezel | |
| dc.date.accessioned | 2023-08-29T07:33:07Z | |
| dc.date.available | 2023-08-29T07:33:07Z | |
| dc.date.issued | 2022-08 | |
| dc.description | DATA AVAILABILITY STATEMENT : Data available on request from the authors. | en_US |
| dc.description.abstract | The effect of various clays nanofillers on the photo-oxidation of polyamide 11 (PA11) has been investigated by accelerated ultraviolet (UV) test up to 780 h. Organo-modified montmorillonite, halloysite nanotubes, and sepiolite were selected and incorporated separately to PA11 at 5 wt.%. The samples were prepared by melt compounding. Fourier transform infrared (FTIR) data showed a linear increase of carbonyl index (CI) in the first 360 h of exposure indicating a rapid oxidation of all samples without any induction period. Further, the nanocomposite samples exhibit faster oxidation kinetics than PA11, being however less pronounced for PA11/sepiolite. This is consistent with both the yellowing index (YI) evolution determined by UV–Vis spectroscopy and also the onset oxidation temperature (OOT) determined by differential scanning calorimetry (DSC). | en_US |
| dc.description.department | Chemical Engineering | en_US |
| dc.description.department | Chemistry | en_US |
| dc.description.librarian | hj2023 | en_US |
| dc.description.sponsorship | The DGRSDT (Direction Générale de la Recherche Scientifique et du développement Technologique) from Algeria. | en_US |
| dc.description.uri | https://onlinelibrary.wiley.com/journal/15213900 | en_US |
| dc.identifier.citation | Dehouche, N., Kaci, M., Focke, W.W. & Van der Merwe, L. 2022, 'Accelerated photo-oxidation of Polyamide 11 nanocomposites under various clays nanofillers', Macromolecular Symposia, vol. 404, no. 1, art. 2100352, pp. 1-3, doi : 10.1002/masy.202100352. | en_US |
| dc.identifier.issn | 1022-1360 (print) | |
| dc.identifier.issn | 1521-3900 (online) | |
| dc.identifier.other | 10.1002/masy.202100352 | |
| dc.identifier.uri | http://hdl.handle.net/2263/92092 | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley | en_US |
| dc.rights | © 2022 Wiley-VCH GmbH. This is the pre-peer reviewed version of the following article : 'Accelerated photo-oxidation of Polyamide 11 nanocomposites under various clays nanofillers', Macromolecular Symposia, vol. 404, no. 1, art. 2100352, pp. 1-3, 2022, doi : 10.1002/masy.202100352.. The definite version is available at : https://onlinelibrary.wiley.com/journal/15213900. | en_US |
| dc.subject | Clays | en_US |
| dc.subject | Nanocomposites | en_US |
| dc.subject | Photo-oxidation | en_US |
| dc.subject | Polyamide 11 (PA11) | en_US |
| dc.subject | Ultraviolet (UV) | en_US |
| dc.subject | Fourier transform infrared (FTIR) | en_US |
| dc.subject | Onset oxidation temperature (OOT) | en_US |
| dc.subject | Differential scanning calorimetry (DSC) | en_US |
| dc.title | Accelerated photo-oxidation of Polyamide 11 nanocomposites under various clays nanofillers | en_US |
| dc.type | Postprint Article | en_US |