Chemistry in four dimensions

dc.contributor.emailjan.boeyens@up.ac.zaen_US
dc.contributor.upauthorBoeyens, Jan Christoffel Antonie
dc.date.accessioned2014-06-04T10:26:46Z
dc.date.available2014-06-04T10:26:46Z
dc.date.issued2013
dc.description.abstractSome chemical phenomena, awkward to rationalize, are argued to originate in the four-dimensional nature of matter in curved space-time. The problem is traced back to the separation of space and time variables in the analysis of fourdimensional events. Althoughmathematically sound, this operation is not physically valid. It destroys the essential non-classical entanglement of space and time, which is recognized in relativistic theory, but not in quantum mechanics. We show that without this approximation the state functions of quantum theory have the same quaternion structure that describes Lorentz transformation and spin. Hypercomplex formulation of four-dimensional motion eliminates several bothersome concepts, such as wave-particle duality and probability density, by providing the logical basis for non-zero commutators in non-classical systems. It shows why chiral states are undefined in quantum theory and why many solid-state transitions appear to be sterically forbidden. A brief introduction to hypercomplex algebra is given as an Appendix.en_US
dc.description.librarianhj2014en_US
dc.description.urihttp://www.springer.com/series/430en_US
dc.identifier.citationBoeyens, JCA 2013, 'Chemistry in four dimensions', Structure and Bonding, vol. 148, pp. 25-47.en_US
dc.identifier.issn0081-5993
dc.identifier.urihttp://hdl.handle.net/2263/39989
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.rights© Springer-Verlag Berlin Heidelberg 2013. The original publication is available at : http://www.springer.com/series/430en_US
dc.subjectd’Alembertianen_US
dc.subjectDirac’s equationen_US
dc.subjectHarmonic functionen_US
dc.subjectSpin functionen_US
dc.subjectQuaternionen_US
dc.titleChemistry in four dimensionsen_US
dc.typePostprint Articleen_US

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