Fischer-type gold(I) carbene complexes stabilized by aurophilic interactions

dc.contributor.authorBezuidenhout, Daniela Ina
dc.contributor.authorVan der Westhuizen, Belinda
dc.contributor.authorRosenthal, Amos J.
dc.contributor.authorWörle, Michael
dc.contributor.authorLiles, David C.
dc.contributor.authorFernandez, Israel
dc.contributor.emaildaniela.bezuidenhout@up.ac.zaen_US
dc.date.accessioned2014-02-04T13:25:50Z
dc.date.issued2014
dc.description.abstractThe synthesis and structure of rare acyclic alkoxy- and aminocarbene complexes of gold(I) are reported, including a novel ferrocenophane dinuclear biscarbene complex. X-Ray diffraction analyses and DFT calculations reveal that these complexes are stabilized by genuine aurophilic interactions.en_US
dc.description.embargo2015-02-28
dc.description.librarianhb2014en_US
dc.description.sponsorshipNational Research Foundation,South Africa (D.I.B., Grant number 76226), and the Spanish MICINN and CAM (I.F., Grants CTQ2010-20714-CO2-01/BQU, Consolider-Ingenio 2010, CSD2007-00006,S2009/PPQ-1634).en_US
dc.description.urihttp://www.rsc.org/daltonen_US
dc.identifier.citationBezuidenhout, DI, Van der Westhuizen, B, Rosenthal, AJ, Wörle, M, Liles, DC & Fernández, I 2014, 'Fischer-type gold(I) carbene complexes stabilized by aurophilic interactions', Dalton Transaction, vol. 43, no. 2, pp. 398-401.en_US
dc.identifier.issn1477-9226 (print)
dc.identifier.issn1364-5447 (online)
dc.identifier.other10.1039/C3DT52961D
dc.identifier.urihttp://hdl.handle.net/2263/33280
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.rights© The Royal Society of Chemistry 2014.en_US
dc.subjectFischer-type gold(I)en_US
dc.subjectCarbeneen_US
dc.subjectComplexes stabilizeden_US
dc.subjectAurophilic interactionsen_US
dc.titleFischer-type gold(I) carbene complexes stabilized by aurophilic interactionsen_US
dc.typeArticleen_US

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