Characterization of the corrosion layer on iron archaeological artefacts from K2 (825-1220 AD), an archaeological site in South Africa

dc.contributor.authorKoleini, Farahnaz
dc.contributor.authorPrinsloo, Linda Charlotta
dc.contributor.authorSchoeman, M.H. Alex
dc.contributor.authorPikirayi, Innocent
dc.contributor.authorChirikure, Shadreck
dc.date.accessioned2013-10-28T06:20:26Z
dc.date.available2013-10-28T06:20:26Z
dc.date.issued2013
dc.description.abstractA study of the composition and phase distribution of the corrosion layers on three ferrous objects, excavated at K2 (Bambandyanalo), an archaeological site in South Africa, was conducted. The objective of the study was to obtain information that can contribute to conservation procedures to be performed on the iron artefacts from this site. Examination of cross sections by means of SEM-EDS, XRD and micro-Raman spectroscopy revealed the same corrosion composition and structure for all the objects under study, namely an internal layer adjacent to the metal surface with ghost inclusions and an external layer containing quartz grains. The study also revealed that the presence of magnetite (Fe3O4), maghemite (γFe2O3) and lepidocrocite (γ-FeOOH) within the internal layer is the only difference between the chemical compositions of iron corrosion products within the two layers. The results also made it possible to retrace the corrosion history during burial and long term storage.en_US
dc.description.librarianhb2013en_US
dc.description.librariancp2013en
dc.description.urihttp://www.ingentaconnect.com/content/maney/sicen_US
dc.identifier.citationKoleini, F, Prinsloo, LC, Schoeman, MHA, Pikirayi, I & Chirikure, S 2013, 'Characterization of the corrosion layer on iron archaeological artefacts from K2 (825-1220 AD), an archaeological site in South Africa', Studies in Conservation, vol. 58, no. 3, pp. 274-282.en_US
dc.identifier.issn2047-0584 (online)
dc.identifier.issn0039-3630 (print)
dc.identifier.other10.1179/2047058412Y.0000000044
dc.identifier.urihttp://hdl.handle.net/2263/32159
dc.language.isoenen_US
dc.publisherManey Publishingen_US
dc.rights© The International Institute for Conservation of Historic and Artistic Works 2013en_US
dc.subjectArchaeologyen_US
dc.subjectIron artefactsen_US
dc.subjectConservationen_US
dc.subjectCorrosionen_US
dc.subjectMicro- Ramanen_US
dc.subjectBambandyanaloen_US
dc.subject.lcshExcavations (Archaeology)en
dc.subject.lcshHistoric sitesen
dc.subject.lcshAntiquitiesen
dc.subject.lcshArchaeological assemblages -- South Africaen
dc.subject.lcshIron -- Corrosionen
dc.subject.lcshRaman spectroscopyen
dc.titleCharacterization of the corrosion layer on iron archaeological artefacts from K2 (825-1220 AD), an archaeological site in South Africaen_US
dc.typePostprint Articleen_US

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