The effect of metallic composition of layered double hydroxide clay on the removal of phenol from aqueous solution
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Date
Authors
Tabana, Lehlogonolo Shane
Labuschagne, F.J.W.J. (Frederick Johannes Willem Jacobus)
Tichapondwa, Shepherd Masimba
Journal Title
Journal ISSN
Volume Title
Publisher
Italian Association of Chemical Engineering
Abstract
The present study focused on the evaluation of Layered Double Hydroxide (LDH) clays containing various
metallic compositions as adsorbents for phenol from wastewater. Neat clays were found to have low phenol
adsorption efficiencies mainly due to poor mixing and incompatibility of the inorganic clays with phenolic water.
Calcination of the clays at 500 °C produced amorphous mixed metal oxides which greatly increased the
Brunauer Emmett Teller (BET) surface areas by more than 200 % from 8.71 to 29.73 m2
/g. The highest phenol
adsorption removal (85 %) was observed within 24 h upon calcination of the clay. The presence of a substantial
amount of zinc in hydrotalcite clay was found to be the main cause of a high phenol removal. Optimisation
studies showed that higher adsorption efficiencies were attainable at pH 7 and the clay was reusable for up to
3 cycles.
Description
Keywords
Clay minerals, Phenol, Layered double hydroxide (LDH), Brunauer Emmett Teller (BET), Metallic composition, Wastewater, Aqueous solution
Sustainable Development Goals
Citation
Tabana L.S., Labuschagne F.J.W.J., Tichapondwa S.M., 2020, The Effect of Metallic Composition of Layered Double
Hydroxide Clay on the Removal of Phenol from Aqueous Solution, Chemical Engineering Transactions, 81, 193-198, DOI:10.3303/CET2081033.