Isothermal vapor-liquid equilibrium data for the 1,1,2,3,3,3-hexafluoroprop-1-ene +1,1,2,2,3,3,4,4-octafluorocyclobutane binary system : measurement and modeling from (292 to 352) K and pressures up to 2.6 Mpa

Abstract

Isothermal vapor–liquid equilibrium data are presented for the 1,1,2,2-tetrafluoroethylene and 1,1,2,3,3,3-hexafluoroprop-1-ene binary system at (248.14, 263.01, and 282.89) K, with pressures ranging from (0.12 to 2.35) MPa. An apparatus based on the “static–analytic” method, equipped with a movable rapid online sampler–injector (ROLSI), was used to undertake the measurements. The combined expanded uncertainties are estimated at 0.11 K, 4 kPa, and 0.012 and 0.009 for the temperature, pressure, and the equilibrium liquid and vapor mole fractions, respectively. The experimental data were correlated with the Peng–Robinson equation of state using the Mathias–Copeman α function, together with the Wong–Sandler mixing rule utilizing the nonrandom two-liquid activity coefficient model.