Morphological and Rheological properties of new quaternized polysulfone with triphenylphosphonium pendant groups

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Authors

Buruiana, L.
Avram, E.
Popa, A.
Stoica, I.
Ioan, S.

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International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics

Abstract

Paper presented at the 9th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Malta, 16-18 July, 2012.
A new quaternized polysulfone with triphenylphosphonium pendant groups was synthesized by reacting chloromethylated polysulfone with triphenylphosphine. The molecular restructurations, generated by hydrogen bonding, electrostatic interactions and association phenomena in ternary quaternized polysulfone/N,N-dimethylformamide (solvent) / water (non- solvent) systems, were evaluated by rheological investigations. The results were correlated with the morphological properties of the films prepared from solutions in solvent/nonsolvent mixtures

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Keywords

Quaternized polysulfone, Triphenylphosphonium pendant, Chloromethylated polysulfone with triphenylphosphine, Rheological, Morphological properties

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Buruiana, L, Avram, E, Popa, A, Stoica, I & Ioan, S 2012, Morphological and Rheological properties of new quaternized polysulfone with triphenylphosphonium pendant groups, Paper presented to the 9th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Malta, 16-18 July, 2012.