Rheological behavior and thermal properties of pitch/poly(vinyl chloride) blends
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Date
Authors
Hlatshwayo, S.R.
Focke, Walter Wilhelm
Ramjee, Shatish
Rand, Brian
Manyala, Ncholu I.
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier
Abstract
The effect of adding poly(vinyl chloride) (PVC) and coke filler on the rheological behavior
and thermal properties of a coal tar pitch was investigated with a view to developing an
appropriate viscoelastic binder for the injection molding of graphite components. Dynamic
mechanical analysis revealed that the pitch formed compatible blends with PVC featuring a
single glass transition temperature (Tg) intermediate to the two parent Tg’s. Adding PVC to
the pitch increased melt viscosity substantially and resulted in strong shear thinning
behavior at high PVC addition levels. Adding coke powder as filler increased the melt viscosity
even further and enhanced shear thinning trends. Pyrolysis conducted in a nitrogen
atmosphere revealed interactions between the PVC and pitch degradation pathways: the
blends underwent significant thermal decomposition at lower temperatures but showed
enhanced carbon yields at high temperatures. Pyrolytic carbon yield at 1000 C was further
improved by a heat treatment (temperature scanned to 400 C) in air or oxygen. However,
carbon yield decreased with addition of PVC. In addition, the degree of ordering attained
following a 1 h heat treatment at 2400 C also decreased with increasing PVC content.
Description
Keywords
Rheological behavior, PVC, Coke filler, Coal tar pitch
Sustainable Development Goals
Citation
S.R. Hlatshwayo, W.W. Focke, S. Ramjee, B. Rand, N. Manyala, Rheological behavior and thermal properties of pitch/poly(vinyl chloride) blends, Carbon, vol 51, pp. 64-71 (2013), doi: 10.1016/j.carbon.2012.08.012