1,3-Bis(2,4,6-trimethylphenyl)-3H imidazol-1-ium tetraoxidorhenate(VII)

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Authors

Landman, Marile
Van der Westhuizen, Belinda
Bezuidenhout, Daniela Ina
Liles, David C.

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Publisher

International Union of Crystallography

Abstract

The title compound, (C21H25N2)[ReO4], was formed as the unexpected product in an attempted synthesis of a rhenium(I)–N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C—H O hydrogen bond.

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Keywords

Single-crystal X-ray study, T = 293 K, R factor = 0.033, wR factor = 0.083, Data-to-parameter ratio = 15.1, Mean (C–C) = 0.003 A°

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Citation

Landman, M, Van der Westhuizen, B, Bezuidenhout, DI & Liles, DC 2011, '1,3-Bis(2,4,6-trimethylphenyl)-3H imidazol-1-ium tetraoxidorhenate(VII)', Acta Crystallographica Section E-Structure Reports Online, vol. E67, part 12, pp. m1897-sup-6.