1,3-Bis(2,4,6-trimethylphenyl)-3H imidazol-1-ium tetraoxidorhenate(VII)
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Date
Authors
Landman, Marile
Van der Westhuizen, Belinda
Bezuidenhout, Daniela Ina
Liles, David C.
Journal Title
Journal ISSN
Volume Title
Publisher
International Union of Crystallography
Abstract
The title compound, (C21H25N2)[ReO4], was formed as the
unexpected product in an attempted synthesis of a
rhenium(I)–N-heterocyclic carbene (NHC) complex. The
compound has crystallographic mirror symmetry with both
the cation and the tetrahedral anion located across a mirror
plane. The cation and anion are linked by a C—H O
hydrogen bond.
Description
Keywords
Single-crystal X-ray study, T = 293 K, R factor = 0.033, wR factor = 0.083, Data-to-parameter ratio = 15.1, Mean (C–C) = 0.003 A°
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Citation
Landman, M, Van der Westhuizen, B, Bezuidenhout, DI & Liles, DC 2011, '1,3-Bis(2,4,6-trimethylphenyl)-3H imidazol-1-ium tetraoxidorhenate(VII)', Acta Crystallographica Section E-Structure Reports Online, vol. E67, part 12, pp. m1897-sup-6.