Browsing Research Articles (Chemistry) by UP Author "Aucamp, Danielle"

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Synthesis of heterobimetallic gold(I) ferrocenyl-substituted 1,2,3-triazol-5-ylidene complexes as potential anticancer agents

Aucamp, Danielle; Kumar, Sreedhar V.; Liles, David C.; Fernandes, Manuel A.; Harmse, Leonie; Bezuidenhout, Daniela Ina (Royal Society of Chemistry, 2018-09)

1,2,3-Triazol-5-ylidene (trz) complexes of gold(I) containing a ferrocenyl substituent on the C4-position of the trz ring were synthesized to yield the neutral heterobimetallic gold(I) trz chlorido (2), gold(I) trz phenyl ...
A triarylated 1,2,3-triazol-5-ylidene ligand with a redox-active ferrocenyl substituent for rhodium(I)-catalyzed hydroformylation of 1-octene

Aucamp, Danielle; Witteler, Tim; Dielmann, Fabian; Siangwata, Shepherd; Liles, David C.; Smith, Gregory S.; Bezuidenhout, Daniela Ina (Wiley, 2017-03)

A series of rhodium(I)–1,2,3-triazol-5-ylidene (trz) complexes are described, containing either a novel triarylated trz ligand A′ (N1, N3-arylated, C4-ferrocenyl) {complexes 1, [Rh(A′)Cl(cod)]; 4, [Rh(A′)Cl(CO)2]}, or ...

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