The carbine complex [MnCp(CO)2C(OEt)(TT)], (TT = 3,6-dimethylthieno[3,2-b]thiophene) 1, was synthesized according to the classical Fisher method. The novel complex was fully characterized using various spectroscopic ...

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The electrochemical behaviour of a series of Fischer ethoxycarbene complexes of the type [(CO)5Crdouble bond; length as m-dashC(OEt)R] with R = 2-thienyl (1), 2-furyl (2), 2-(N-methylpyrrolyl) (3), N-methyl-2-(2′-thienyl)pyrrole) ...

[Rh((C4H3S)COCHCO(C4H3S))(CO)(PPh3)] crystals stack in one dimensional linear chains in the solid state, with slightly slipped π-stacking of the thienyl groups of one molecule and the β-diketonato backbone of a neighbouring ...

Nine new Ni(II)-NHC complexes, [CpNiBr(NHC)], were synthesised from nickelocene and the corresponding symmetric or asymmetric alkyl/-benzyl/phenylethyl imidazolium bromide ligands in relatively high yield. Access to each ...

Solid state crystal data of three tris(b-diketonato)metal(III) complexes (M = Cr or Co), representative of the three different molecular symmetries that these complexes can obtain, namely D3, C3 or C1 symmetry, are ...

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Density functional theory calculations showed that rotation of the (P(OCH2)3CCH3) group in the rhodium-acetylacetonato complex [Rh(acac)(CO)(P(OCH2)3CCH3)] has a negligible influence on the energy of the complex. Density ...

The solid state single crystal structures of [Rh(β-diketonato)(CO)2], where β-diketonato = (R1COCHCOR2)−, with R1, R2 = CF3, C4H3S (1), C4H3S, C4H3S (2), Ph, C4H3S (3) and CF3, Ph (4), show that these complexes in some ...

The chlorine coordinated ligands in [Ti(tfba)2Cl2] (Htfba = 4,4,4-trifluoro-1-(phenyl)-1,3-butanedione = PhCOCH2COCF3) are very susceptible to hydrolysis and even with trace amounts of water, the formation of hydrolysed ...