Van der Westhuizen, Danielle; Slabber, Cathryn A.; Fernandes, Manuel A.; Joubert, Daniel Francois; Kleinhans, George; Van der Westhuizen, Carl Johan; Stander, Andre; Munro, Orde; Bezuidenhout, Daniela Ina(Wiley, 2021-06)
The syntheses of bis(triazolium)carbazole precursors
and their corresponding coinage metal (Au, Ag) complexes
are reported. For alkylated triazolium salts, di- or tetranuclear
complexes with bridging ligands were isolated, ...
Bezuidenhout, Daniela Ina; Kleinhans, George; Guisado-Barrios, Gregorio; Liles, David C.; Ung, Gael; Bertrand, Guy(Royal Society of Chemistry, 2014-03)
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the ...
Kleinhans, George; Guisado-Barrios, Gregorio; Liles, David C.; Bertrand, Guy; Bezuidenhout, Daniela Ina(Royal Society of Chemistry, 2016-01)
An air-stable rhodium(I)-oxygen adduct featuring a CNC-pincer
ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homodimerization
and hydrothiolation of alkynes, affording the gemenyne
and α-vinyl sulfide isomers, ...
