It is illustrated that the electrochemical redox potentials of chromium(0) Fischer carbene complexes containing a heteroaromatic substituent can be determined to a high degree of accuracy from the gas phase density functional ...
Gostynski, Roxanne; Van Rooyen, Petrus H.; Conradie, Jeanet(Elsevier, 2016-09)
The solid state crystal data of a mer isomer of the [Mn(CF3COCHCOC4H3S)3] complex, [Mn(tfth)3], exhibits
elongation Jahn-Teller distortion (elongation of the metal-ligand bonds along the z-axis and shortening
of the ...
Gostynski, Roxanne; Van Rooyen, Petrus H.; Conradie, Jeanet(Elsevier, 2020-02)
An X-ray study was conducted on tris(trifluoroacetylacetonato)-manganese(III). The two different molecules in the unit cell exhibit a distorted octahedral geometry and moderate compression Jahn–Teller distortion respectively. ...
