Laser-induced fluorescence of polycyclic aromatic hydrocarbons : an approach to gas standards

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dc.contributor.author Forbes, Patricia B.C.
dc.contributor.author True, Andreas
dc.contributor.author Rohwer, Egmont Richard
dc.date.accessioned 2010-03-24T06:27:31Z
dc.date.available 2010-03-24T06:27:31Z
dc.date.issued 2011-03
dc.description.abstract Rapid methods are needed to analyse air pollutants such as polycyclic aromatic hydrocarbons (PAHs). Reliable semi-quantitative gas standards were required for the development of a laser-induced fluorescence (LIF) method for polycyclic aromatic hydrocarbon analysis, based on sampling of air onto multi-channel polydimethylsiloxane rubber traps. Easily constructed diffusion tubes provided naphthalene vapour at ~2 ng s-1. A gas chromatographic fraction collection method for loading less volatile PAHs onto the traps from a flame ionization detector outlet was developed and optimized. The accuracy of the method, which can be further optimized, was sufficient for initial LIF screening tests to flag samples exceeding threshold PAH levels for subsequent quantitative GC–MS analysis. en
dc.identifier.citation Forbes, PBC, True, A & Rohwer, ER 2011, 'Laser-induced fluorescence of polycyclic aromatic hydrocarbons : an approach to gas standards', Environmental Chemistry Letters, vol. 9, no. 1, pp. 7-12, doi:10.1007/s10311-009-0238-6. [http://www.springerlink.com/content/110367/?p=49b32ff9fc20474691dfe046d8b24b63π=3] en
dc.identifier.issn 1610-3653
dc.identifier.other 10.1007/s10311-009-0238-6
dc.identifier.uri http://hdl.handle.net/2263/13710
dc.language.iso en en
dc.publisher Springer en
dc.rights Springer en
dc.subject Gas standards en
dc.subject.lcsh Polycyclic aromatic hydrocarbons en
dc.subject.lcsh Laser photochemistry en
dc.subject.lcsh Air -- Pollution -- Measurement en
dc.subject.lcsh Air -- Analysis en
dc.subject.lcsh Gas chromatography en
dc.subject.lcsh Polydimethylsiloxane en
dc.title Laser-induced fluorescence of polycyclic aromatic hydrocarbons : an approach to gas standards en
dc.type Postprint Article en


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