Abstract:
The effect of implantation temperature on the migration behaviour of xenon (Xe) implanted into glassy carbon
and the effect of annealing on radiation damage retained by ion implantation were investigated. Glassy carbon
substrates were implanted with 320 keV Xe+ to a fluence of 2 × 1016 cm-2. The implantation process was performed at room temperature (RT) and 100 ◦C Some of the as-implanted samples were isochronally annealed in
vacuum at temperatures ranging from 300 ◦C to 700 ◦C in steps of 100 ◦C for 10 h. The as-implanted and
annealed samples were characterized using Rutherford backscattering spectrometry (RBS) and Raman spectroscopy. The RT implanted depth profiles indicated that the migration of Xe towards the surface of glassy carbon
was accompanied by a loss of Xe ions. The samples implanted at 100 ◦C indicated no diffusion or loss of Xe after
annealing at 300 ◦C. However, annealing at temperatures ranging from 400 ◦C to 700 ◦C resulted in a slight shift
in the Xe profile tail-end towards the bulk of glassy carbon. The diffusion coefficients (D) in the temperature
range of 300 ◦C–700 ◦C for the RT and 100 ◦C implanted samples, activation energies (Ea), and pre-exponential
factors (Do), were extracted. The values of D ranged from (9.72 ± 0.48) × 10-21 to (1.87 ± 0.09) × 10-20 m2
/s
with an activation energy of (6.25 ± 0.31) × 10-5 eV for RT implanted samples, and the samples implanted at
100 ◦C, D ranged from (3.85 ± 0.19) × 10-21 to (6.96 ± 0.34) × 10-20 m2
/s with activation energy of (4.10 ±
0.02) × 10-5 eV. The Raman analysis revealed that implantation at the RT amorphised the glassy carbon structure
while the samples implanted at 100 ◦C showed mild damage compared to RT implantation. Annealing of the RTimplanted sample resulted in some recovery of the damaged region as a function of increasing annealing
temperature.
